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Known examples of interpenetration
Current to 31/10/05 - Now with Selected Pictures!!
Dr. Stuart Batten
School of Chemistry
Monash University 3800
Australia
Ph: +61 3 9905 4606
Fax: +61 3 9905 4597
E-mail: stuart.batten@sci.monash.edu.au
In Review: "Interpenetrating Nets: Ordered, Periodic Entanglement", Stuart R. Batten and Richard Robson, Angew. Chem. Int. Ed., 1998, 37, 1460-1494; Angew. Chem., 1998, 110, 1558-1595. (Or "Catenane and Rotaxane Motifs in Interpenetrating and Self-Penetrating Coordination Polymers", Stuart R. Batten and Richard Robson, in Molecular Catenanes, Rotaxanes and Knots, A Journey Through the World of Molecular Topology, eds. J.-P. Sauvage and C. Dietrich-Buchecker, Wiley-VCH, Weinheim, 1999, 77-105.)
If you find this table useful, please cite “Topology of Interpenetration”, CrystEngComm, 2001, 3, 67-73.
http://xlink.rsc.org/?DOI=10.1039/B102400k
** A number of entries have been added or corrected thanks to the extensive CSD and ICSD database searches contained in the following papers: V.A. Blatov, L. Carlucci and D.M. Proserpio, CrystEngComm, 2004, 6, 377-395; I.A. Baburin, V.A. Blatov, L. Carlucci, G. Ciani and D.M. Proserpio, J. Solid State Chem., 2005, 178, 2471-2493.
*** Every effort has been made to ensure this table is both comprehensive and correct, but if you know of any possible omissions or errors (and it is highly likely there will be examples of each), I would greatly appreciate the feedback. Compliments are also accepted! ***
- 1D→1D parallel
- 1D→2D parallel
- 1D→2D inclined
- 1D→3D inclined
- 2D→2D parallel (6,3)
- 2D→2D parallel (4,4)
- 2D→2D parallel (other)
- 2D→3D parallel
- 2D inclined (6,3)
- 2D inclined (4,4)
- 2D inclined with more than 2 stacks
- 2D inclined (other)
- 2D inclined and parallel
- 3D (8,3)
- 3D (8,10)
- 3D (10,3)-a
- 3D (10,3)-b
- 3D (10,3) other
- 3D (12,3)
- 3D 3-connected other
- 3D diamond
- 3D 4-connected other
- 3D 5-connected
- 3D 6-connected α-Po
- 3D 6-connected other
- 3D 8-connected
|
|
|
| Compound |
Notes |
# |
Reference |
| 3D 4-connected diamond [ top ] |
| 2 |
| Various organic polymers. |
Diamond (proposed). See also 'Misc related' section. |
2
or
3• |
D.B. Alward, D.J. Kinning, E.L. Thomas and L.J. Fetters, Macromolecules, 1986, 19, 215; H. Hasegawa, H. Tanaka, K. Yamasaki and T. Hashimoto, Macromolecules, 1987, 20, 1651; D.M. Anderson and E.L. Thomas, Macromolecules, 1988, 21, 3221; E.L. Thomas, D.B. Alward, D.J. Kinning, D.C. Martin, D.L. Handlin, Jr. and L.J. Fetters, Macromolecules, 1986, 19, 2197; E.L. Thomas, D.M. Anderson, C.S. Henkee and D. Hoffman, Nature, 1988, 334, 598; Y. Mogi, K. Mori, Y. Matsushita and Y. Noda, Macromolecules, 1992, 25, 5412; Y. Mogi, H. Kotsuji, Y. Kaneko, K. Mori, Y. Matsushita and I. Noda, Macromolecules, 1992, 25, 5408; Y. Matsushita, M. Tamura and I. Noda, Macromolecules, 1994, 27, 3680. |
| Two lipid-water phases |
See also 'Misc related' section. |
2• |
W. Longley and T.J. McIntosh, Nature, 1983, 303, 612. |
| M2O, (M = Cu, Ag, Pd, Zr, Pt), Au2S, Ag2-xAux
|
Note that although the structure of Pb2O was assigned as being isomorphous with Cuprite (Cu2O), based on powder X-ray data, in a 1926 paper, later papers conclude that Pb2O does not exist.
|
2• |
R. Restori and D. Schwarzenbach, Acta Crystallogr., Sect. B, 1986, 42, 201-208; A. Kirfel and K.D. Eichhorn, Acta Crystallogr., Sect. A, 1990, 46, 271-284; Z.G. Pinsker and R.M. Imamov, Kristallogr., 1964, 9, 413-415; T. Yamaguti, Proc. Phys.: Math. Soc. Jpn., 1938, 20, 230-241; M.C. Neuburger, Z. Phys., 1930, 67, 845-850; P. Niggli, Z. Kristallogr., 1922, 57, 253-299; J. Kumar and R. Saxena, J. Less-Comm. Met., 1989, 147, 59-71; P. Norby, R.E. Dinnebier and A.N. Fitch, Inorg. Chem., 2002, 41, 3628-3637; R.W.G. Wyckoff, Am. J. Sci., 1922, 3, 184-188; V.I. Khitrova and V.V. Klechkovskaya, Kristallogr., 1985, 30, 70-73; K. Ishikawa, T. Isonaga, S. Wakita and Y. Suzuki, Solid State Ionics, 1995, 79, 60-66; J.C.W. Folmer, P. Hofman and G.A. Wiegers, J. Less-Comm. Met., 1976, 48, 251-268. For Pb2O, see A. Ferrari, Gazz. Chim. It., 1926, 56, 630-637; R.W.G. Wyckoff, Crystal Structures, 2nd Ed., Vol. 1, Wiley, New York, 331; ICSD entry 28838. For "non-existence" of Pb2O, see: M. Le Blanc and E. Eberius, Z. Physik. Chem., 1932, A160, 129-40; R. Fricke and P. Ackermann, Z. Physik. Chem., 1932, A161, 227-230; R. David, Compt. Rend., 1955, 240, 782-784. |
| CaWO4 (scheelite) and related structures; ZrSiO4 (zircon) and related structures. |
Diamond nets can be constructed if only consider 4 shorest contacts. Approx. 340 codes in ICSD. |
2• |
Ref. 8 in O. Ermer and A. Eling, Angew. Chem. Int. Ed. Engl., 1988, 27, 829; R.W.G. Wyckoff, Crystal Structures, 2nd Ed., Vol. 3, Wiley, New York, 15-23; D. de Waal and K.-J. Range, Z. Naturforsch., 1996, 51b, 1365-1367, and references therein. |
| NH4XO4), X = I, Re |
H-bonded nets. |
2 |
W. Levason and M. Webster, Acta Crystallogr., Sect. C, 1999, 55, IUC9900052; J. Beintema, Strukturbericht, 1937, 3, 421-423; H. Braekken, Norsk Videnskab Selskab Forh., 1928, 1, 149-152; R.J.C. Brown and S.L. Segel, Acta Crystallogr., Sect. B, 1980, 36, 2195-2198; G.J. Kruger and E.C. Reynhardt, Acta Crystallogr., Sect. B, 1978, 34, 259-261; I.P. Swainson and R.J.C. Brown, Acta Crystallogr., Sect. B, 1997, 53, 78-81; B.M. Powell, R.J.C. Brown, A.M. Harnden and J.K. Reid, Acta Crystallogr., Sect. B, 1993, 49, 463-468. |
| MO.2B2O3, M = Li2, Mg, Zn, Cd, Mn, Fe, Co, Ni, Hg |
M links 2 nets in Li ??? Others?? |
2• |
J. Krogh-Moe, Acta Crystallogr., 1962, 15, 190-193; J. Krogh-Moe, Acta Crystallogr., Sect. B, 1968, 24, 179-181; M. Natarajan, R. Faggiani and I.D. Brown, Cryst. Struct. Comm., 1979, 8, 367-370; H. Bartl and W. Schuckmann, Neues Jahrb. Miner. Monatsh., 1966, 142-148; E. Ecker, Thesis, Technische Hochschule Karlsruhe, Germany, 1966; M. Martinez-Ripoll, S. Martinez-Carrera and S. Garcia-Blanco, Acta Crystallogr., Sect. B, 1971, 27, 672-677; M. Ihara and J. Krogh-Moe, Acta Crystallogr., 1966, 20, 132-134; J.L.C. Rowsell, N.J. Taylor and L.F. Nazar, J. Solid State Chem., 2003, 174, 189-197; M. Weil, Acta Crystallogr., Sect. E, 2003, 59, 40-42; M. Martinez-Ripoll and S. Garcia-Blanco, An. Fisica, 1970, 66, 209-210; S.C. Abrahams, J.L. Bernstein, P. Gibart and R.C. Sherwood, J. Chem. Phys., 1974, 60, 1899-1905; S.F. Radaev, L.A. Muradyan, L.F. Malakhova, Y.A. Burak and V.I. Simonov, Kristallogr., 1989, 34, 1400-1407. |
| α-Na2O.3B2O3 |
Na links 2 nets ??? |
2• |
J. Krogh-Moe, Acta Crystallogr., Sect. B, 1974, 30, 747. |
| M2O.4B2O3 M = Ag, Na, Ba1/2 |
Ag links 2 nets ??? |
2• |
J. Krogh-Moe, Acta Crystallogr., 1965, 18, 77-81; A. Hyman, A. Perloff, F. Mauer and S. Block, Acta Crystallogr., 1967, 22, 815-821; J. Krough-Moe, Acta Crystallogr., Sect. B, 1969, 25, 2153-2154; N. Penin, M. Touboul and G. Nowogrocki, Solid State Sci., 2003, 5, 559-564; R.S. Bubnova, F. Shepelev Yu, N.A. Sennova and S.K. Filatov, Z. Kristallogr., 2002, 217, 444-450; N. Penin, M. Touboul and G. Nowogrocki, J. Solid State Chem., 2002, 168, 316-321. |
| β-M2O.4B2O3 M = Ag, Na |
M links nets??
|
2 |
N. Penin, M. Touboul and G. Nowogrocki, Solid State Sci., 2003, 5, 559-564; N. Penin, M. Touboul and G. Nowogrocki, J. Solid State Sci., 2002, 168, 316-321. |
| M2O.5B2O3, M = K (α- and β- forms), Rb (α- and β- forms), Cs (β- and γ- forms), Tl |
|
2• |
J. Krogh-Moe, Acta Crystallogr., 1965, 18, 1088; J. Krogh-Moe, Acta Crystallogr., Sect. B, 1972, 28, 168; J. Krogh-Moe, Ark. Kemi, 1959, 14, 439; H. Bartl and W. Schuckmann, Neues Jahrb. Miner. Monatsh., 1966, 142; M. Touboul, C.R. Acad. Sci., Ser. C, 1973, 277, 1025; M. Touboul and G. Nowogrocki, J. Solid State Chem., 1998, 136, 216-220; R.S. Bubnova, I.G. Polyakova, J.E. Anderson and S.K. Filatov, Glass Phys. Chem., 1999, 25, 183; M.G. Krzhizhanovskaya, R.S. Bubnova, S.K. Filatov, A. Belger and P. Paufler, Z. Kristallogr., 2000, 215, 740; N. Penin, L. Seguin, M. Touboul and G. Nowogrocki, J. Solid State Chem., 2001, 161, 205; N. Penin, Thesis, Amiens, France, 2001 (referenced in M. Touboul, N. Penin and G. Nowogrocki, Solid State Sci., 2003, 5, 1327-1342). |
| LiAlB2O5 |
|
2 |
M. He, X.L. Chen, Y.C. Lan, H. Li and Y.P. Xu, J. Solid State Chem., 1999, 156, 181-184. |
| Li2(AlB5O10) |
|
2 |
M. He, H. Li, X.-L. Chen, Y.-P. Xu and T. Xu, Acta Crystallogr., Sect. C, 2001, 57, 1010-1011. |
| K2[PdSe10] |
Each net has different composition. |
2• |
K.W. Kim and M.G. Kanatzidis, J. Am. Chem. Soc., 1992, 114, 4878-4883. |
| Cs2PdSe8 |
Diamond topology not recognised. Each net has same composition. Commented upon in later paper by MGK. |
2 |
J. Li, Z. Chen, R.-J. Wang, and J.Y. Lu, J. Solid State Chem., 1998, 140, 149-153. |
| Some high pressure forms of ice (Ice VII and VIII) |
Diamond nets - Ice VII is orientationally disordered, while Ice VIII is not. |
2• |
B. Kamb and B.L. Davis, Proc. Natl. Acad. Sci. U.S.A., 1964, 52, 1433-1439; A.J. Brown and E. Whalley, J. Chem. Phys., 1966, 45, 4360; E. Whalley, D.W. Davidson and J.B.R. Heath, J. Chem. Phys., 1966, 45, 3976; C. Weir, S. Block and G. Piermarini, J. Res. Natl. Bur. St. Ser. C, 1965, 69, 275; B. Kamb, J. Chem. Phys., 1965, 43, 3917; J.D. Jorgensen and T.G. Worlton, J. Chem. Phys., 1985, 83, 329-333; W.F. Kuhs, J.L. Finney, C. Vettier and D.V. Bliss, J. Chem. Phys., 1984, 81, 3612-3623; J.M. Besson, P. Pruzan, S. Klotz, G. Hamel, B. Silvi, R.J. Nelmes, J.S. Loveday, R.M. Wilson and S. Hull, Phys. Rev. B, 1994, 49, 12540-12550; J.D. Jorgensen, R.A. Beyerlein, R.A. Watanabe and T.G. Worlton, J. Chem. Phys., 1984, 81, 3211-3214. |
| 2,6-dimethylideneadamantane-1,3,5,7-tetracarboxylic acid |
H-bonded; four structures with different guests, one of which interpenetrates asymmetrically. |
2• |
O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1991, 74, 825. |
| Ln2(C6H2O4)3.24H2O, Ln = Ce, La, Gd, Y, Yb, Lu |
Diamond net with one link being a H-bonded water cluster. H-bonding between nets. |
2• |
B.F. Abrahams, J. Coleiro, B.F. Hoskins and R. Robson, Chem. Commun., 1996, 603; B.F. Abrahams, J. Coleiro, K. Ha, B.F. Hoskins, S.D. Orchard and R. Robson, J. Chem. Soc., Dalton Trans., 2002, 1586-1594. |
| K2M[NC5H3(CO2)2-2,3]2, M = Mn, Zn |
|
2• |
S.O.H. Gutschke, A.M.Z. Slawin and P.T. Wood, J. Chem. Soc., Chem. Commun., 1995, 2197. |
| [Sn5S9O2][HN(CH3)3]2 |
S linked tetrahedral Sn10S20O4 clusters. |
2• |
J.B. Parise and Y. Ko, Chem. Mater., 1994, 6, 718. |
| Si(NCN)2 |
|
2• |
R. Riedel, A. Greiner, G. Miehe, W. Dressler, H. Fuess, J. Bill and F. Aldinger, Angew. Chem. Int. Ed. Engl., 1997, 36, 603-6; see also P. Kroll, R. Riedel and R. Hoffmann, Phys. Rev. B, 1999, 60, 3126-3139. |
| CBr4.Hexamethylenetetramine |
Net linked by N-Br interactions. |
2• |
D.S. Reddy, D.C. Craig, A.D. Rae and G.R. Desiraju, J. Chem. Soc., Chem. Commun., 1993, 1737 (see also related structures in D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Chem. Soc., Chem. Commun., 1994, 1457-1458; D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Am. Chem. Soc., 1996, 118, 4090-4093). |
| Tetrakis(4-nitrophenyl)methane.G, G = THF, dioxane, nitrobenzene, 4-bromoanisole, anisole, phenetole, p-xylene, shlorobenzene |
Net held together by weak C-H...O and π...π interactions. |
2 |
R. Thaimattam, F. Xue, J.A.R.P. Sharma, T.C.W. Mak and G.R. Desiraju, J. Am. Chem. Soc., 2001, 123, 4432-4445. |
| Si(C5H4NO)4.G, G = 4CH3CO2H, 4CH3CH2CO2H, CH3(CH2)3CO2H, 0.5CH3(CH2)3CO2H.CH3CO2H |
H-bonded nets |
2• |
X. Wang, M. Simard and J.D. Wuest, J. Am. Chem. Soc., 1994, 116, 12119-12120; D. Su, X. Wang, P. Deschatelets, L. Vaillancourt, M. Simard and J.D. Wuest, Polymer Prepr., 1995, 36, 554-555; O. Saied, T. Maris and J.D. Wuest, J. Am. Chem. Soc., 2003, 125, 14956-14957. |
| [M(CO)3(μ3-OH)]4 + L, M = Mn or Re, L = H-bonded bridging ligand |
L H-bonds between tetrahedral clusters. |
2, 3, or 4• |
S.B. Copp, S. Subramanian and M.J. Zaworotko, J. Am. Chem. Soc., 1992, 114, 8719; S.B. Copp, S. Subramanian and M.J. Zaworotko, J. Chem. Soc., Chem. Commun., 1993, 1078; M.J. Zaworotko, Chem. Soc. Rev., 1994, 23, 283; M.J. Zaworotko, S. Subramanian and L.R. MacGillivray, Mater. Res. Soc. Symp. Proc., Optical and Magnetic properties of Organic Solid State Materials, 1994, 328, 107; S.B. Copp, K.T. Holman, J.O.S. Sangster, S. Subramanian and M.J. Zaworotko, J. Chem. Soc., Dalton Trans., 1995, 2233. |
| SCd8(SCH(CH3)C2H5)12(CN)2 |
|
2• |
I.G. Dance, Perspectives in Coordination Chemistry, eds. A.F. Williams, C. Floriani and A. Merbach, Verlag Helvetica Chimica Acta, Basel, Switzerland, 1992, 165. |
| Cd17S4(SCH2CH2OH)26 |
Clusters forming nodes. |
2• |
T. Vossmeyer, G. Reck, L. Katsikas, E.T.K. Haupt, B. Schulz and H. Weller, Science, 1995, 267, 1476. |
| M(CN)2, M = Zn, Cd, Be, Mg |
|
2• |
H.S. Zhdanov, C. R. Acad. Sci. URSS (or Dokl. Akad. Nauk?), 1941, 31, 352-354; E. Shugam and H.S. Zhdanov, Acta Physiochim. URSS, 1945, 20, 247-252; B.F. Hoskins and R. Robson, J. Am. Chem. Soc., 1990, 112, 1546-1554; T. Kitazawa, S. Nishikiori, R. Kuroda and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 1029; D.J. Williams, D.E. Partin, F.J. Lincoln, J. Kouvetakis and M. O'Keeffe, J. Solid State Chem., 1997, 134, 164-169; E.A. Shugam and G.S. Zhdanov, Zh. Fiz. Khim., 1945, 19, 515-518; O. Reckeweg and A. Simon, Z. Naturforsch., Teil B, 2002, 57, 895-900; D. Williams, B. Pleune, K. Leinenweber and J. Kouvetakis, J. Solid State Chem., 2001, 159, 244-250. |
| MGa(CN)4, M = Li, Cu |
|
2• |
L.C. Brousseau, D. Williams, J. Kouvetakis and M. O'Keeffe, J. Am. Chem. Soc., 1997, 119, 6292-6296. |
| M[B(CN)4], M = Ag, Cu, Na, Li, NH4, Rb, Cs, Tl, K |
For Rb, Cs, Tl, K, this only applies if only shortest M-N interactions taken into account, and next shortest (ca. 0.1-0.2 Å longer) ignored. Otherwise, a single 4,8-connected net.
|
2 |
E. Bernhardt, G. Henkel and H. Willner, Z. Anorg. Allg. Chem., 2000, 626, 560-568; E. Bessler, Z. Anorg. Allg. Chem., 1977, 430, 38-42; T. Kuppers, E. Bernhardt, H. Willner, H.W. Rohm and M. Kockerling, Inorg. Chem., 2005, 44, 1015-1022; D. Williams, B. Pleune, J. Kouvetakis, M.D. Williams and R.A. Anderson, J. Am. Chem. Soc., 2000, 122, 7735-7741. |
| Li[Al(CN)4] |
|
2 |
G. Wittig and H. Bille, Z. Naturforsch., 1951, 6b, 226. |
| Li[Co(CO)4] |
Isomorphous with Zn(CN)2. |
2• |
P. Klufers, Z. Kristallogr., 1984, 167, 275-286; P. Klufers, Z. Kristallogr., 1983, 162, 138. |
| Mn(CN)2 |
Proposed on basis of XRPD, etc. |
2 |
J.L. Manson, W.E. Buschmann and J.S. Miller, Angew. Chem. Int. Ed., 1998, 37, 783-784; Angew. Chem., 1998, 110, 815-817; J.L. Manson, W.E. Buschmann and J.S. Miller, Inorg. Chem., 2001, 40, 1926-1935. |
| Cu(4-cyanopyridine)2(ClO4) |
|
2• |
B.F. Hoskins, J. Liu and R. Robson, unpublished results. |
| Cd(en)Cd(CN)4 |
Four-connected net which can be related to a diamond net where the nodes are Cd(CN)4 squares. With Cd nodes, topology is (43.62.8) or gismondine (gis). |
2• |
S. Nishikiori, T. Iwamoto and Y. Yoshino, Chem. Lett., 1979, 1509; S. Nishikiori and T. Iwamoto, J. Incl. Phenom., 1985, 3, 283 (as interpreted in O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1991, 74, 825). |
| Li5B7S13 |
Nodes are B/S clusters. See below also. |
2• |
F. Hiltmann, P. zum Hebel, A. Hammerschmidt and B. Krebs, Z. Anorg. Allg. Chem., 1993, 619, 293-302. |
| Na6B10S18, Li6+2x[B10S18]Sx, Li5B7S13, Ag6B10S18, Li5.88B10S18 |
Nodes are B/S clusters. See above also. |
2 |
O. Conrad, C. Jansen and B. Krebs, Angew. Chem. Int. Ed., 1998, 37, 3208-18; Angew. Chem., 1998, 110, 3396-3407; C. Puttmann, P. zum Hebel, A. Hammerschmidt and B. Krebs, Acta Crystallogr., Sect. A, 1990, 46, C279-80; A. Hammerschmidt, P. zum Hebel, F. Hiltmann and B. Krebs, Z. Anorg. Allg. Chem., 1996, 622, 76-84; P. zum Hebel, B. Krebs, M. Grune and W. Muller-Warmuth, Solid State Ionics, 1990, 43, 133-42; M. Grune, W. Muller-Warmuth, P. zum Hebel and B. Krebs, Solid State Ionics, 1993, 66, 165-73; M. Grune, W. Muller-Warmuth, P. zum Hebel and B. Krebs, Solid State Ionics, 1995, 78, 305-13; B. Krebs and H. Diercks, Z. Anorg. Allg. Chem., 1984, 518, 101-114; A. Hammerschmidt, A. Lindermann, M. Doech and B. Krebs, Solid State Sci., 2002, 4, 1449-1455. |
| Cu(3,3’-bipy)2X, X = BF4, PF6 |
|
2• |
S. Lopez, M. Kahraman, M. Harmata and S.W. Keller, Inorg. Chem., 1997, 36, 6138-6140. |
| [Me2NH2]6In10S18 |
In10S2010- act as tet. centres. |
2• |
C.L. Cahill, Y. Ko and J.B. Parise, Chem. Mater., 1998, 10, 19-21. |
| [Et2NH2]6In10S18 |
In10S2010- act as tet. centres. Isomorph. with above structure. |
2 |
C.L. Cahill and J.B. Parise, J. Chem. Soc., Dalton Trans., 2000, 1475-82. |
| [pyrollidine]6In10S18 |
In10S2010- act as tet. centres. Isomorph.? with above structure. |
2 |
Cahill, et al., unpublished results (cited in C.L. Cahill and J.B. Parise, J. Chem. Soc., Dalton Trans., 2000, 1475-82). |
| (Ph3P)2(Cl)(CO)Os{Si(OH)2O(OH)2Si}- Os(CO)(Cl)(PPh3)2 |
CSD refcode LADDEZ; Net defined by 6PE interactions. |
2 |
in I. Dance and M. Scudder, J. Chem. Soc., Dalton Trans., 2000, 1587-1594. |
| [Cd(py-CO2)2(EtOH)][EtOH] |
|
2 |
W. Lin, R. Xiong, O. Evans and Z. Wang, unpublished results (mentioned in O.R. Evans, R.-G. Ziong, Z. Wang, G.K. Wong and W. Lin, Angew Chem. Int. Ed., 1999, 38, 536-8; Angew. Chem., 1999, 111, 557-9). |
| CuCN(pyz) |
Interpenetration and diamond topology missed by authors. |
2 |
R. Kuhlman, G.L. Schimek and J.W. Kolis, Polyhedron, 1999, 18, 1379-1387. |
| CuCN(Mepyz) |
Interpenetration missed by authors. |
2 |
O. Teichert and W.S. Sheldrick, Z. Anorg. Allg. Chem., 1999, 625, 1860-1865. |
| [Cd(isonicotinate)2(EtOH)][EtOH], [Cd(isonicotinate)2(H2O)][pyrazine] |
|
2 |
O.R. Evans, Z. Wang, R.-G. Xiong, B.M. Foxman and W. Lin, Inorg. Chem., 1999, 38, 2969-2973. |
| [Cd(isonicotinate)2(H2O)][DMF] |
|
2 |
J.-H. Liao, C.-Y. Lai, C.-D. Ho and C.-T. Su, Inorg. Chem. Commun., 2004, 7, 402-404. |
| ZnI2, Δ-GeS2, BeCl2, BeI2, ZnBr2, HgI2 (one orange phase) |
Two nets with M4X6 adamantane-like clusters as tetrahedral centres.
|
2 |
P.H. Fourcroy, D. Carre and J. Rivet, Acta Crystallogr., Sect. B, 1978, 34, 3160-3162; M.J. MacLachlan, S. Petrov, R.L. Bedard, I. Manners and G.A. Ozin, Angew. Chem. Int. Ed., 1998, 37, 2076-2079; Angew. Chem., 1998, 110, 2185-2189; E. Spundflasche, H. Fink and H.J. Seifert, Z. Anorg. Allg. Chem., 1995, 621, 1723-1726; S.I. Troyanov, Zh. Neorg. Khim., 2000, 45, 1619-1624; C. Chieh and M.A. White, Z. Kristallogr., 1984, 166, 189-197; H. Hostettler and D. Schwarzenbach, Acta Crystallogr., Sect. B, 2002, 58, 914-920. |
| M(NH2)2, M = Be, Mg, Mn, Zn |
Two nets with ZnI2 structure. H-bonds between nets.
|
2 |
H. Jacobs, Z. Anorg. Allg. Chem., 1971, 382, 97-109; 1976, 427, 1-7; ; B. Froehling, G. Kreiner and H. Jacobs, Z. Anorg. Allg. Chem., 1999, 625, 211-216. |
| Li(dioxane)2.5TaCl4S.1/2dioxane |
Diamond nets if take into account S…S interaction of 3.561 Å. |
2 |
S. Hasche, C. Mock, J. Otto, F. Schweppe, K. Kirschbaum, B. Krebs and A.A. Pinkerton, Inorg. Chim. Acta, 2000, 298, 9-15. |
| [AgL]BF4.1.5C6H6, L = cyanotris(4-cyanophenyl)methane |
|
2 |
W. Choe, Y.-H. Kiang, Z. Xu and S. Lee, Chem. Mater., 1999, 11, 1776-1783. |
| β-Ca3Ga2N4 |
Ignoring Ca…N interactions, two interpenetrating nets with adamantane-like Ga4N6 clusters linked by four further bridging N atoms. |
2 |
S.J. Clarke and F.J. DiSalvo, J. Alloys Compd., 1998, 274, 118-121 (as quoted in M. Schindler, F.C. Hawthorne and W.H. Baur, Acta Crystallogr., Sect. B, 1999, 55, 811-829). |
| Na2[SnAs2] |
Ignoring Na cations, two interpenetrating netws withadamantane-like Sn4As6 clusters as the tetrahedral nodes. |
2 |
M. Asbrand and B. Eisenmann, Z. Naturforsch., 1993, 48B, 452-456. |
| [Cu(en)2]Cu7Cl11 |
Two interpenetrating diamondoid Cu/Cl nets. Long (2.7 - 2.8 Å) Cu…Cl interactions to (Cu(en)2)2+ cations cross-link nets. |
2 |
J.R.D. DeBord, Y. Lu, C.J. Warren, R.C. Haushalter and J. Zubieta, Chem. Commun., 1997, 1365-1366 (as quoted in M. Schindler, F.C. Hawthorne and W.H. Baur, Acta Crystallogr., Sect. B, 1999, 55, 811-829). |
| Cu4I4(μ-Me612Se3)2, Me612Se3 = 3,3,7,7,11,11-hexamethyl-1,5,9-triselanacyclohexadecane |
Two interpenetrating diamondoid nets, not mentioned in original paper. |
2 |
R.D. Adams, K.T. McBride and R.D. Rogers, Organomet., 1997, 16, 3895-3901 (mentioned in N.R. Brooks, A.J. Blake, N.R. Champness, P.A. Cooke, P. Hubberstey, D.M. Proserpio, C. Wilson and M. Schroder, J. Chem. Soc., Dalton Trans., 2001, 456-465.) |
| Cd4In16S33.(H2O)20(C10H28N4)2.5 |
Tetrahedral nodes are (Cd4In16S35)2- clusters sharing S atoms. |
2 |
H. Li, J. Kim, T.L. Groy, M. O'Keeffe and O.M. Yaghi, J. Am. Chem. Soc., 2001, 123, 4867-4868. See also C. Wang, Y. Li, X. Bu, N. Zheng, O. Zivkovic, C.-S. Yang and P. Feng, J. Am. Chem. Soc., 2001, 123, 11506-7 for analogous structures with different cations and Zn, Mn or Co in place of Cd. |
| Various cation-templated Zn/Ga/In/Cu/Sn/Ge chalcogenides |
Tetrahedral nodes are clusters. |
2 |
N. Zheng, X. Bu, B. Wang and P. Feng, Science, 2002, 298, 2366-2369; C. Wang, X. Bu, N. Zheng and P. Feng, J. Am. Chem. Soc., 2002, 124, 10268-10269; X. Bu, N. Zheng, Y. Li and P. Feng, J. Am. Chem. Soc., 2002, 124, 12646-12647; N. Zheng, X. Bu and P. Feng, J. Am. Chem. Soc., 2003, 125, 1138-1139; C. Wang, X. Bu, N. Zheng and P. Feng, Chem. Commun., 2002, 1344-1355; N. Zheng, X. Bu and P. Feng, Nature, 2003, 426, 428-432. |
| M(LMn(CO)3)2, L = benzoquinone, M = Mn, Co, Zn |
|
2 |
M. Oh, G.B. Carpenter and D.A. Sweigart, Angew Chem. Int. Ed., 2001, 40, 3191-3194; Angew. Chem., 2001, 113, 3291-3294; M. Oh, G.B. Carpenter and D.A. Sweigart, Organometallics, 2003, 22, 2364-2366. |
| [Mn(hfac)2]2(tetranitroxide), hfac = hexafluoroacetylacetonate, tetranitroxide = tetrakis-[4-(N-tert-butyl-N-oxyamino)phenyl]methane |
|
2 |
F. Mathevet and D. Luneau, J. Am. Chem. Soc., 2001, 123, 7465-6. |
| Zn(ADC)2.(HTEA)2, ADC = acetylenedicarboxylate, TEA = triethylamine |
|
2 |
J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M. O'Keeffe and O.M. Yaghi, J. Am. Chem. Soc., 2001, 123, 8239-8247. |
| Zn2(ATB)(H2O).(H2O)3(DMF)3, ATB = adamantanetetrabenzoate |
|
2 |
J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M. O'Keeffe and O.M. Yaghi, J. Am. Chem. Soc., 2001, 123, 8239-8247. |
| Ag(bpp)2(X), bpp = 1,3-bis(4-pyridyl)propane, X = BF4, ClO4 |
|
2 |
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, CrystEngComm, 2002, 4(22), 121-129. |
| [CuL2(H2O)2]X, X = (ClO4)(OH)(H2O)2.5 or (PF6)2(H2O)1.25, L = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole |
|
2 |
M. Du, X.-H. Bu, Y.-M. Guo, H. Liu, S.R. Batten, J. Ribas and T.C.W. Mak, Inorg. Chem., 2002, 41, 4904-4908; M. Du, Y.-M. Guo, S.-T. Chen, X.-H. Bu, S.R. Batten, J. Ribas and S. Kitagawa, Inorg. Chem., 2004, 43, 1287-1293. |
| NH4(bpedo)2PF6.3H2O, bpedo = trans-bis(4-pyridyl)ethylene dioxide |
H-bonded nets. |
2 |
B.-Q. Ma, H.-L. Sun and S. Gao, Chem. Commun., 2003, 2164-2165. |
| M(im)2, M = Hg, Cd, Him = imidazole |
Solved by PXRD initially, then single crystal for Cd. Normal mode. |
2 |
N. Masciocchi, G.A. Ardizzoia, S. Brenna, F. Castelli, S. Galli, A. Maspero and A. Sironi, Chem. Commun., 2003, 2018-2019; Y.-Q. Tian, L. Xu, C.-X. Cai, J.-C. Wei, Y.-Z. Li and X.-Z. You, Eur. J. Inorg. Chem., 2004, 1039-1044. |
| Cd(bpp)(NO2-BDC)(H2O).0.25H2O, bpp = 1,3-bis(4-pyridyl)propane, NO2-BDCH2 = 5-nitro-1,3-benzenetricarboxylic acid |
|
2 |
J. Luo, M. Hong, R. Wang, R. Cao, L. Han and Z. Lin, Eur. J. Inorg. Chem., 2003, 2705-2710. |
| [Zn(DPT)2(H2O)2] [Zn(DPT)2(MeCN)2](ClO4)4.2MeCN, DPT = 2,4-di-(4-pyridyl)-1,3,5-triazine |
|
2 |
M. Sasa, K. Tanaka, X.-H. Bu, M. Shiro and M. Shionoya, J. Am. Chem. Soc., 2001, 123, 10750-10751. |
| KH2PO4 (KDP) |
Two interpenetrating nets if only count shortest K-O interactions (e.g. 2.834 Å) and ignore second shortest (e.g. 2.900 Å). Probably better described as a single diamond net of H-bonded H2PO4 anions (e.g. O...O = 2.498 Å) with K counterions! |
2 |
S. Endo, T. Chino, S. Tsuboi and K. Koto, Nature, 1989, 340, 452-455. |
| [Ag(C25H20N2O2)2]SbF6 |
|
2 |
Y.-B. Dong, P. Wang, R.-Q. Huang and M.D. Smith, Inorg. Chem., 2004, 43, 4727-4739. |
| Cd(HBTC)(TMD)(H2O).4.5H2O, H3BTC = 1,3,5-benzenetricarboxylic acid, TMD = 4,4'-trimethylenedipyridine |
|
2 |
F.A.A. Paz and J. Klinowski, Inorg. Chem., 2004, 43, 3882-3893. |
| Ag(malononitrile)2BF4 |
Asymmetric interpenetration. |
2 |
A. Westcott, N. Whitford and M.J. Hardie, Inorg. Chem., 2004, 43, 3663-3672. |
| Ca1.5Li11(In22Li4S42).44H2O |
Large cluster as node. |
2 |
N. Zheng, X. Bu and P. Feng, Angew. Chem. Int. Ed., 2004, 43, 4753-4755. |
| [{Cu(acac)(phen)}2(bpp)](ClO4)2.6H2O, phen = 1,10-phenanthroline, bpp = 1,3-bis(4-pyridyl)propane |
Nodes are pairs of dimeric complexes twisted around each other and held together by lipophilic interactions. Nodes then connected by pi-pi interactions. |
2 |
A.M. Madalan, V.C. Kravtsov, Y.A. Simonov, V. Voronkova, L. Korobchenko, N. Avarvari and M. Andruh, Cryst. Growth Des., 2005, 5, 45-47. |
| Ag2(pcp)2(HO2CC4F8CO2)2.toluene, pcp = [2.2]paracyclophane |
|
2 |
S.Q. Liu, H. Konaka, T. Kuroda-Sowa, M. Maekawa, Y. Suenaga, G.L. Ning and M. Munakata, Inorg. Chim. Acta, 2005, 358, 919-926. |
| M[Ru(acac)2(CN)2]2, M = Mn, Co |
|
2 |
W.-F. Yeung, W.-L. Man, W.-T. Wong, T.-C. Lau and S. Gao, Angew. Chem. Int. Ed., 2001, 40, 3031-3033; W.-F. Yeung, P.-H. Lau, T.-C. Lau, H.-Y. Wei, H.-L. Sun, S. Gao, Z.-D. Chen and W.-T. Wong, Inorg. Chem., 2005, 44, 6579-6590. |
| LiM2(NCN)X3, M = Sr, Eu, X = Br, I |
One net has adamantine-like Li4X6 cages connecting through shared Li atoms, the other contains cube-like M4N4 cages connected by bridging NCN ligands. Although the two nets have different SBU clusters, the overall topology of both is diamond with the clusters as nodes.
|
2 |
W. Liao and R. Dronskowski, Z. Anorg. Allg. Chem., 2005, 631, 1953-1956; W. Liao, J. von Appen and R. Dronskowski, Chem. Commun., 2004, 2302-2303; W. Liao, C. Hu, R.K. Kremer and R. Dronskowski, Inorg. Chem., 2004, 43, 5884-5890. |
| Ag(tpb)(NO3)(MeOH), tpb = 3,3',5,5'-tetrakis(4-pyridyl)bimesityl |
If ligand considered as tetrahedral node, then topology is diamond. If ligand considered as two linked 3-connecting nodes, then becomes a 3,4-connected net with Wells' (8,3/4)-b (or (83)2(86)) topology. |
2 |
R. Natarajan, G. Savitha, P. Dominiak, K. Wozniak and J.N. Moorthy, Angew. Chem. Int. Ed., 2005, 44, 2115-2119. |
| (MeLi)4(tmeda)2, tmeda = N, N, N',N'-tetramethylethylendiamine |
If Li atoms nodes, then topology is (33.123) dia-a topology. If Li4Me4 clusters nodes, then diamond. |
2 |
H. Koster, D. Thoennes and E. Weiss, J. Organomet. Chem., 1978, 160, 1-5. |
| [Tl(t-BuO)3Sn]2Mo(CO)4 |
|
2 |
M. Veith, S. Weidner, K. Kunze, D. Kafer, J. Hans and V. Huch, Coord. Chem. Rev., 1994, 137, 297-322. |
| Mo2(OAc)4.0.5hmt.0.5CH2Cl2, hmt = hexamethylenetetraamine |
Abstract says topology PtS, but actually diamond. |
2 |
H. Ackermann, F. Weller, R. Stief and K. Dehnicke, Z. Anorg. Allg. Chem., 2000, 626, 1496-1498. |
| [Et4N]6 [Na14Mo24P17O97(OH)31] .xH2O |
Mo24 cluster nodes. |
2 |
R.C. Haushalter and F.W. Lai, Angew. Chem. Int. Ed. Engl., 1989, 28, 743-746. |
| Cd2.75L(H2O)7 .1.5NO3.7H2O.MeOH, H4L = N, N'-bis(phosphonomethyl)-1,10-diaza-18-crown-6 |
|
2 |
J.-G. Mao, Z. Wang and A. Clearfield,
Inorg. Chem., 2002, 41, 3713-3720. |
| SbCl3L, L = p-diacetylbenzene |
|
2 |
W.A. Baker and D.E. Williams, Acta Crystallogr., Sect. B, 1978, 34, 1111-1116. |
| Fe(CO)4(HgSCN)2 |
Hg2Fe(CO)4 clusters as nodenodes gives diamond nets; Hg as nodes gives (10,3)-a. |
2 |
A.E. Mauro, R.H.A. Santos, M.T.P. Gambardella and R.H.P. Francisco, Polyhedron, 1987, 6, 1273-1277. |
| Cd(nic)2(H2O), Hnic = nicotinic acid |
|
2 |
W. Clegg, J.T. Cressey, A. McCamley and B.P. Strauchan, Acta Crystallogr., Sect. C, 1995, 51, 234-235. |
| (SnMe3)3CrO4(OH) |
|
2 |
A.M. Domingos and G.M. Sheldrick, J. Chem. Soc., Dalton Trans., 1974, 477-480. |
| Zn(HCN4)2 |
|
2 |
X.-S. Wang, Y.-Z. Tang, X.-F. Huang, Z.-R. Qu, C.-M. Che, P.W.H. Chan and R.-G. Xiong, Inorg. Chem., 2005, 44, 5278-5285. |
| TaPS6 |
(10,3)-a topology, but if Ta-Ta dinuclear units in taken as nodes, then diamond topology. |
2 |
S. Fiechter, W.F. Kuhs and R. Nitsche, Acta Crystallogr., Sect. B, 1980, 36, 2217-2220. |
| [Ir4(CO)8F2](Sb2F11)2 |
Ir cluster as node. |
2 |
I.-C. Hwang and K. Seppelt, Inorg. Chem., 2003, 42, 7116-7122. |
| (NH4)3Cu4Ho2Br13 and Rb3Cu4Tm2Br13 |
|
2 |
M.S. Wickleder, A. Bohnsack and G. Meyer, Z. Anorg. Allg. Chem., 1996, 622, 675-678; A. Bohnsack and G. Meyer, Z. Kristallogr. New Cryst. Struct., 1997, 212, 1. |
| (NH4)5Ce[Ni(NO2)6]2 |
|
2 |
A. Ferrari, L. Cavalca and M. Nardelli, Gazz. Chim. Ital., 1951, 81, 964-981. |
| M(AlCl4)2, M = Ca, Yb, Sr |
|
2 |
P. Stegmueller, Dissertation Universitaet Karlsruhe, 1997, pp. 1-193; K. Mueller, Dissertation Universitaet Karlsruhe, 1993, pp. 1-158. (ICSD entries 56727-56730). |
| CsHSO4 |
|
2 |
B.V. Merinov, Kristallogr., 1997, 42, 906-917; Z. Jirak, M. Dlouha, S. Vratislav, A.M. Balagurov, A.I. Beskrovnji, V.I. Gordelii, I.D. Datt and L.A. Shuvalov, Phys. Status Solidi A, 1987, 100, K117-K122; V. Varma, N. Rangavittal and C.N.R. Rao, J. Solid State Chem., 1993, 106, 164-173; Z. Nozik Yu, O.I. Lyakhovitskaya, N.M. Shchagina and V.A. Sarin, Kristallogr., 1990, 35, 658-660; B.V. Merinov, A.I. Baranov, L.A. Shuvalov and B.A. Maksimov, Kristallogr., 1987, 32, 86-92. |
| NH4Br I and NH4I III |
H-bonded nets. |
2 |
V.N. Kolomiichuk and V.F. Dvoryankin, Kristallogr., 1964, 9, 50-56; V. Hovi, K. Paavola and E. Nurmi, Ann. Acad. Sci. Fenn. Ser. A 6: Physica, 1969, 328, 1-8. |
| (D2O)2(DF)3 |
H-bonded nets. |
2 |
W. Poll, M. Lohmeyer and D. Mootz, Z. Naturforsch., Teil B, 1989, 44, 1359-1364. |
| NH4[F(HF)3] |
H-bonded nets. |
2 |
D. Mootz and W. Poll, Z. Naturforsch., Teil B, 1984, 39, 290-297. |
| Cyanamide, NH2CN |
H-bonded; racemic pair. If N atoms nodes, then two (10,3)-a nets; if whole molecule node, the diamond nets. |
2• |
M.A. Brook, R. Faggiani, C.J.L. Lock and D. Seebach, Acta Crystallogr., Sect. C, 1988, 44, 1979-1981; B.H. Torrie, R. von Dreele and A.C. Larson, Molec. Phys., 1992, 76, 405-410; C.L. Christ, Acta Crystallogr., 1951, 4, 77. |
| |
|
|
|
| 3 |
| Tetrasodium 1,3,5,7-Adamantanetetracarboxylate Tetrahydrate |
H-bonded. |
3• |
O. Ermer and L. Lindenberg, Chem. Ber., 1990, 123, 1111. |
| 2,6-Dioxoadamantane-1,3,5,7-tetracarboxylic acid (hydrate) |
H-bonded; contains acetic acid guests. |
3• |
O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1988, 71, 1084. |
| 3,3-Bis(carboxymethyl) glutaric acid ("methanetetraacetic acid") |
H-bonded. |
3• |
O. Ermer and A. Eling, Angew. Chem. Int. Ed. Engl., 1988, 27, 829. |
| all-trans-cyclobutane-1,2,3,4-tetracarboxylic acid |
H-bonded. |
3• |
O. Ermer and M. Schank, unpublished results (as referenced in O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1991, 74, 825). |
| 4,4’,4’’,4’’’-tetraphenylmethanecarboxylic acid |
H-bonded. |
3• |
B.F. Hoskins, A. Liang and R. Robson, unpublished results. |
| Cu(CN)(4-cyanopyridine) |
|
3• |
D.T. Cromer and A.C. Larson, Acta Crystallogr., Sect. B, 1972, 28, 1052. |
| Ag2(OOC-(CH2)2-COO) |
Ag4 cluster bridged by chelating bridges. |
3• |
A. Michaelides, V. Kiritsis, S. Skoulika and A. Aubry, Angew. Chem. Int. Ed. Engl., 1993, 32, 1495. |
| [Cd(mea)(dahxn){Ni(CN)4}].H2O, mea = 2-Aminoethanol, dahxn = 1,6-Diaminohexane |
|
3• |
H. Yuge, S. Nishikiori and T. Iwamoto, Acta Crystallogr., Sect. C, 1996, 52, 575. |
| [Cu(DMTPN)2]X(DMTPN)(thf), X = BF4, ClO4, DMTPN = 2,3-dimethylterephthalonitrile |
|
3• |
T. Kuroda-Sowa, M. Yamamoto, M. Munakata, M. Seto and M. Maekawa, Chem. Lett., 1996, 349; T. Kuroda-Sowa, T. Horino, M. Yamamoto, Y. Ohno, M. Maekawa and M. Munakata, Inorg. Chem., 1997, 36, 6382-6389. |
| Cu(L)2PF6, L = 2,7-diazapyrene |
Unusual ('abnormal') mode of interpenetration noted by Ciani et al. |
3 |
A.J. Blake, N.R. Champness, A.N. Khlobystov, D.A. Lemenovskii, W.-S. Li and M. Schroder, Chem. Commun., 1997, 1339-1340. See also L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur. J., 2002, 8, 1520-1526. |
| C(p-C6H4X)4, X = Br, I |
Isomorphous structures of alternating C and X4 'synthons' as the tetrahedral nodes. |
3 |
D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Am. Chem. Soc., 1996, 118, 4090-4093; R. Thaimattam, D.S. Reddy, F. Xue, T.C.W. Mak, A. Nangia and G.R. Desiraju, New. J. Chem., 1998, 22, 143-148. |
| Tetraphenylmethane.CBr4 |
Alternating methane and CBr4 tetrahedral centres, connected by Br...Ph interactions; isomorphous with the above structure. However, in Cryst. Eng. paper Desiraju says that there is no interpenetration in this - isomorphous may just mean has diamond net. |
3? |
D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Am. Chem. Soc., 1996, 118, 4090-4093; A. Anthony, G.R. Desiraju, R.K.R. Jetti, S.S. Kuduva, N.N.L. Madhavi, A. Nangia, R. Thaimattam and V.R. Thalladi, Cryst. Eng., 1998, 1, 1-18. |
| Zn(py-CO2)2 |
Acentric nets. |
3 |
O.R. Evans, R.-G. Ziong, Z. Wang, G.K. Wong and W. Lin, Angew Chem. Int. Ed., 1999, 38, 536-8; Angew. Chem., 1999, 111, 557-9. |
| Tetrakis(4-ethynylphenyl)methane |
4-connecting nodes are alternating methane and (CC-H)4 clusters held together by CC-H...CC interactions. |
3 |
E. Galoppini and R. Gilardi, Chem. Commun., 1999, 173-4. |
| 4-bromo and 4- ethynyl substituted tetraphenylmethanes |
Isomorphous with above structure held together by weak intermolecular interactions. |
3 |
W. Guo, E. Galoppini, R. Gilardi, G.I. Rydja and Y-H. Chen, Cryst. Growth Design, 2001, 1, 231-7. |
| [CuCN.Me3SnCN.pyz] |
Distorted because of different length bridges. |
3 |
E. Siebel, A.M.A. Ibrahim and R.D. Fischer, Inorg. Chem., 1999, 38, 2530-2532. |
| [CdL2.G2](NO3)2, L = pyCH2-C6F4-CH2py, G = phenyl acetate, N-methylaniline, toluene, α-methylestyrene, m-xylene, o-methoxyaniline, benzyl methyl ether, biphenyl |
Diamond nets; full structure reported on phenyl acetate. |
3 |
K. Kasai, M. Aoyagi and M. Fujita, J. Am. Chem. Soc., 2000, 122, 2140-2141. |
| UP4S12 |
U4+ bridged by P2S62- ligands. |
3 |
C. Gieck, F. Rocker, V. Ksenofontov, P. Gutlich and W. Tremel, Angew. Chem. Int. Ed., 2001, 40, 908-911. |
| [Cu(pn)2][Mn(dca)4], pn = 1,3-diaminopropane, dca = dicyanamide |
|
3 |
Z.-M. Wang, B.-W. Sun, J. Luo, S. Gao, C.-S. Liao, C.-H. Yan and Y. Li, Inorg. Chim. Acta, 2002, 332, 127-134. |
| NiL2, L = isonicotinate |
|
3 |
T.-B. Lu and R.L. Luck, Acta Crystallogr., Sect. C, 2002, 58, m152-4. |
| 3,7-Diazabicyclo[3.3.1]nonane-2,6-dione-1,5-dicarboxamide |
H-bonded nets. Normal interpenetration, but two nets of one chirality, one of the other. |
3 |
R.G. Kostyanovsky, K.A. Lyssenko, D.A. Lenev and I.A. Bronzova, Tetrahedron: Asymmetry, 2002, 13, 2697-2701. |
| (NIPA)2.HEL, NIPA = 5-nitroisophthalic acid, HEL = hexahelicene |
Nets defined by O-H...O hydrogen bonds in conjunction with either C-H...O or pi...pi interactions (both alternatives give the same topology). |
3 |
O. Ermer and J. Neudorfl, Helv. Chim. Acta, 2001, 84, 1268-1313. |
| Zn(dimb)2(ClO4)2, dimb = 1,3-di(imidazole-1-yl-methyl)-5-methyl-benzene |
|
3 |
Y. Ma, W. Huang, J. Yao, B. Li, S. Gou and H.-K. Fun, J. Mol. Struct., 2003, 658, 51-58. |
| Tetrakis(3,5-dihydroxyphenyl)silane.G, G = 2.0 ethyl acrylate, 2.7 ethyl acetate, 3.3 THF, or 3.3 dioxolane |
H-bonded nets. Weaker H-bonding interactions between nets. |
3 |
O. Saied, T. Maris, X. Wang, M. Simard and J.D. Wuest, J. Am. Chem. Soc., 2005, 127, 10008-10009. |
| Cu(BCDC)2PF6, BCDC = N,N'-bis(4-cyanophenyl)-(1R,2R)-diaminocyclohexane |
|
3 |
S.P. Anthony and T.P. Radhakrishnan, Cryst. Growth Des., 2004, 4, 1223-1227. |
| CuL(L1).2H2O, L = 1,1'-(1,4-butanediyl)bis(imidazole), H2L1 = fumaric acid |
Normal mode. |
3 |
J. Yang, J.-F. Ma, Y.-Y. Liu, S.-L. Li and G.-L. Zheng, Eur. J. Inorg. Chem., 2005, 2174-2180. |
| CuL2(H2O)(ClO4)2.solvate, L = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole |
|
3 |
J.-P. Ma, Y.-B. Dong, R.-Q. Huang, M.D. Smith and C.-Y. Su, Inorg. Chem., 2005, 44, 6143-6145. |
| Cat.H2CTA, Cat = NH4+, NH2NH3+, OHNH3+, H3CTA = 1,3-cis,5-cis-cyclohexanetricarboxylic acid |
H-bonded nets defined by anions, however cations also H-bond and crosslink nets. |
3 |
B.R. Bhogala, P. Vishweshwar and A. Nangia, Cryst. Growth Des., 2005, 5, 1271-1281. |
| PI4[Al(OC(CF3)3)4] |
Nets defined by I...F interactions. |
3 |
M. Gonsior, I. Krossing, L. Muller, I. Raabe, M. Jansen and L. van Wullen, Chem. Eur. J., 2002, 8, 4475-4492. |
| Zn(β-alaninato)2 |
|
3 |
C.-H. Ng, Z.-Y. Zhou, H.-K. Fun, S.-B. Teo, S.-G. Teoh, P. Naumov and S.W. Ng, Main Group Metal Chem., 2001, 24, 747-748. |
| Ag(MeCN)(N(NO2)2) |
|
3 |
H.-G. Ang, W. Fraenk, K. Karaghiosoff, T.M. Klapotke, P. Mayer, H. Noth, J. Sprott and M. Warchhold, Z. Anorg. Allg. Chem., 2002, 628, 2894-2900. |
| Cu3(CN)3(pyz)2 |
Paper says 2 nets, but actually 3. |
3 |
D.J. Chesnut, D. Plewak and J. Zubieta, J. Chem. Soc., Dalton Trans., 2001, 2567-80. |
| [CN3H6]2[Cd(C4H4O4)2] |
Paper says 2 nets, but actually 3. |
3 |
R. Vaidhyanathan, S. Natarajan and C.N.R. Rao, Inorg. Chem., 2002, 41, 5226-5234. |
| CsCo(CO)4 |
|
3 |
P. Klufers, Z. Kristallogr., 1983, 165, 217-226; P. Klufers, Z. Kristallogr., 1983, 162, 138. |
| Tetrakis[(4-nitrophenoxy)methyl]methane |
Nets defined by C-H...O interactions; phenyl embraces between nets. |
3 |
D. Laliberte, T. Maris and J.D. Wuest, CrystEngComm, 2005, 7, 158-160. |
| Pentaerythrityl tetrakis(4-bromobenzyl ether) |
Nets defined by Br...pi interactions. |
3 |
D. Laliberte, N. Raymond, T. Maris and J.D. Wuest, Acta Crystallogr., Sect. E, 2005, 61, o601-o603. |
| Tetrakis[(4-aminophenoxy)methyl]methane |
Each molecule connected to 8 others via N-H...N interactions, however can be regarded as a diamond nets if the nodes alternate between the central C atoms and H-bonded square ring motifs. |
3 |
D. Laliberte, T. Maris, E. Demers, F. Helzy, M. Arseneault and J.D. Wuest, Cryst. Growth Des., 2005, 5, 1451-1456. |
| Ag3CuS2 (Jalpaite) |
Abnormal interpenetration? |
3 |
C.L. Baker, F.J. Lincoln and A.W.S. Johnson, Aust. J. Chem., 1992, 45, 1441-1449. |
| H2Te2O3F4 |
H-bonded nets; (10,3)-b if Te nodes, diamond if dimeric molecules nodes. |
3 |
J.C. Jumas, M. Maurin and E. Philippot, J. Fluor. Chem., 1976, 8, 329-340. |
Continued >>
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